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Title: Synthesis, Absortion and Emission Properties of a New Family of Styryl Coumarins. Potential Utility as Memory Media
Authors: Martins, Sérgio
Avó, João
Parola, António
Lima, João
Branco, Paula
Pereira, António
Issue Date: 18-Jul-2012
Publisher: 6SPJ-OCS
Abstract: SYNTHESIS, ABSORPTION AND EMISSION PROPERTIES OF A NEW FAMILY OF STYRYL COUMARINS. POTENTIAL UTILITY AS MEMORY MEDIA Sérgio Martins,[a] João Avó, [b] A. Jorge Parola, [b] João C. Lima, [b] Paula S. Branco[b] and António Pereira[a] [a] Centro de Química, Departamento de Química, Universidade de Évora, Évora, Portugal, [b] REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Portugal Photochromism, the reversible transformation between two molecular forms that have different absorption spectra, resulting from photo-irradiation, has applicability in several fields including light modulation materials, optical recording materials, optical switches and photochromic ink.[1] The switching from one molecular state to another is dependent upon the efficiency of light absorption by the chromophore. Coumarins are an old class of compounds of natural occurrence in several plant families. On substitution with various functional groups at different positions the coumarin chromophores expand their interesting proprieties. In recent years we have devoted some interest to the study of coumarin chromophores, with special emphasis on their synthesis and photophysical properties.[2] We have been particularly interested in the extension of the -delocalized system of the coumarin chromophore at the 3-position which allowed us to obtain derivatives with promising fluorescent behavior. Here we present the synthesis of a new coumarin family, the 5-styryl coumarins 1 and the study of the effect of the extension of the -delocalized system of the coumarin chromophore at the 5-position (Fig.1). The synthesized compounds present E-Z isomerization around the carbon-carbon double bond which can potentially be envisaged to be used as a memory media. Figure1 Acknowledgments: Thanks are due to the Fundação para a Ciência e Tecnologia (Portugal), for partial financial support FCOMP-01-0124-FEDER-007448. [1] a) H. Bouas-Laurent, H. Durr, Pure Appl. Chem. 2001, 73, 639-665; b) V. I. Minkin, Chem. Rev. 2004, 104, 2751-2776; c) M. Irie, Chem. Rev. 2000, 100, 1685-1716. [2] a) J. Gordo, J. Avó, A. J. Parola, J. C. Lima, A. Pereira, P. S. Branco, 2011, 13, 5112–5115; b) S. M. A. Martins, P. S. Branco, A. M. D. R. L. Pereira, J. Braz. Chem. Soc. 2012; c) S. Martins, P. S. Branco, M. C. de la Torre, M. A. Sierra, A. Pereira, Synlett 2010, 2918-2922.
Type: lecture
Appears in Collections:CQE - Comunicações - Em Congressos Científicos Internacionais
QUI - Comunicações - Em Congressos Científicos Internacionais

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