Please use this identifier to cite or link to this item:
http://hdl.handle.net/10174/7172
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Full metadata record
| DC Field | Value | Language |
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| dc.contributor.author | Burke, Anthony | - |
| dc.contributor.author | Marques, Carolina | - |
| dc.date.accessioned | 2013-01-10T12:09:04Z | - |
| dc.date.available | 2013-01-10T12:09:04Z | - |
| dc.date.issued | 2012-09-01 | - |
| dc.identifier.pagina | 7211-7216 | - |
| dc.identifier.issn | 0040-4020 | - |
| dc.identifier.uri | http://hdl.handle.net/10174/7172 | - |
| dc.description.abstract | The rhodium-NHC catalyzed arylation reaction of ethyl glyoxalate with aryl and alkyl boronic acids provides an efficient method for the synthesis of alpha-hydroxyesters. A wide range of alpha-hydroxyesters (up to 12) were prepared in good to excellent yields. KO'Bu was the base of choice, along with tert-amyl alcohol as the solvent. As far as we are aware, this is the first report of this catalytic arylation, using rhodium-NHC catalysts with this specific substrate type | por |
| dc.language.iso | por | por |
| dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | por |
| dc.rights | restrictedAccess | por |
| dc.subject | Catálise | por |
| dc.subject | alfa-Hidroxiester | por |
| dc.title | Expeditious and novel synthesis of alpha-hydroxyesters via rhodium-NHC catalyzed arylation of ethyl glyoxalate | por |
| dc.type | article | por |
| dc.identifier.volume | 68 | - |
| dc.identifier.revista | Tetrahedron | - |
| dc.identifier.numrev | 35 | - |
| dc.identifier.authoremail | ajb@uevora.pt | - |
| dc.identifier.authoremail | carolsmarq@gmail.com | - |
| dc.peerreviewed | no | por |
| dc.identifier.scientificarea | 307 | por |
| dc.identifier.doi | 10.1016/j.tet.2012.05.129 | - |
| Appears in Collections: | CQE - Publicações - Artigos em Revistas Internacionais Com Arbitragem Científica
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CQE - Publicações - Artigos em Revistas Internacionais Com Arbitragem Científica /
