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http://hdl.handle.net/10174/5893
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| Title: | The benzilic ester rearrangement: synthesis of labelled compounds and theoretical studies |
| Authors: | Marques, Carolina S.
Ramalho, J. P. Prates
Burke, Anthony J. |
| Keywords: | benzilic ester rearrangement
labelling studies
fukui function
density functional theory |
| Issue Date: | 2009 |
| Citation: | Marques, Carolina S.; Ramalho, J. P. Prates; Burke, Anthony J.The benzilic ester rearrangement: synthesis of labelled compounds and theoretical studies, Journal of Physical Organic Chemistry, 22, 8, 735-739, 2009. |
| Abstract: | 1,3-Diphenyl-2(13C)-hydroxy-3-methoxypropan-1-one was synthesised and used to probe the mechanism of a benzilic ester rearrangement (BER). Computational studies suggest that the preferred site of attack of the nucleophile in this benzilic ester rearrangement is on C-14. On the basis of these results a new reaction mechanism is proposed. |
| URI: | http://hdl.handle.net/10174/5893 |
| Type: | article |
| Appears in Collections: | QUI - Publicações - Artigos em Revistas Internacionais Com Arbitragem Científica
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