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|Title: ||The benzilic ester rearrangement: synthesis of labelled compounds and theoretical studies|
|Authors: ||Marques, Carolina S.|
Ramalho, J. P. Prates
Burke, Anthony J.
|Keywords: ||benzilic ester rearrangement|
density functional theory
|Issue Date: ||2009|
|Citation: ||Marques, Carolina S.; Ramalho, J. P. Prates; Burke, Anthony J.The benzilic ester rearrangement: synthesis of labelled compounds and theoretical studies, Journal of Physical Organic Chemistry, 22, 8, 735-739, 2009.|
|Abstract: ||1,3-Diphenyl-2(13C)-hydroxy-3-methoxypropan-1-one was synthesised and used to probe the mechanism of a benzilic ester rearrangement (BER). Computational studies suggest that the preferred site of attack of the nucleophile in this benzilic ester rearrangement is on C-14. On the basis of these results a new reaction mechanism is proposed.|
|Appears in Collections:||QUI - Publicações - Artigos em Revistas Internacionais Com Arbitragem Científica|
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